The gas phase reaction of chlorine with chloroform is described by the following reaction:
Cl? + CHCl? ? HCl + CCl?
A proposed mechanism for this reaction involves three steps:
i) Cl?? 2Cl ; a very fast process in both directions,
ii) Cl + CHCl? ? HCl + CCl? ; a very slow process
iii) CCl? + Cl ? CCl? ; a fast process
Derive the overall rate law in differential form for the rate of consumption of Cl?.
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